Case Study
Passage with linked questions
Case Set 1
Case AnalysisPassage
A nuclear physics student is studying the composition of various atomic nuclei in the laboratory. She observes that chlorine has two naturally occurring isotopes: one with mass 34.98 u (abundance 75.4%) and another with mass 36.98 u (abundance 24.6%). She also notes that all isotopes of chlorine have 17 protons in their nuclei but differ in neutron number. During her study, she recalls that James Chadwick in 1932 bombarded beryllium nuclei with alpha particles and discovered neutrons, earning him the 1935 Nobel Prize in Physics. She further notes that a free neutron decays into a proton, electron, and antineutrino with a mean life of about 1000 seconds, yet inside a nucleus it remains stable.
Question 1: Define isotopes and state the number of neutrons in each of the two naturally occurring isotopes of chlorine (atomic number 17).
- Isotopes are nuclides of the same element that have the same number of protons (same atomic number Z) but differ in their number of neutrons (different mass number A).
- For chlorine (Z=17): Isotope with mass number 35 has 35 - 17 = 18 neutrons; Isotope with mass number 37 has 37 - 17 = 20 neutrons.
Question 2: Calculate the average atomic mass of chlorine using its two isotopes with masses 34.98 u and 36.98 u with relative abundances 75.4% and 24.6% respectively.
- Average atomic mass = (75.4 × 34.98 + 24.6 × 36.98) / 100
- = (2637.492 + 909.708) / 100 = 3547.2 / 100 = 35.47 u
Question 3: Chadwick's experiment established the existence of neutrons. Explain why the hypothesis that the neutral radiation in the experiment consisted of photons was rejected, and describe the significance of the neutron being stable inside the nucleus but unstable outside it.
- If the neutral radiation were photons, the conservation of energy and momentum required the photons to have energies far exceeding what the alpha-beryllium bombardment could provide — this was physically impossible.
- Chadwick assumed the radiation consisted of neutral particles (neutrons) of mass nearly equal to the proton mass, which satisfied both energy and momentum conservation consistently.
- A free neutron decays (mean life ~1000 s) into a proton, electron, and antineutrino; inside the nucleus, nuclear forces stabilize the neutron, which is essential for nuclear structure and stability of heavy nuclei.